Is NF3 Polar or Nonpolar?

Is Nf3 polar?

Many people are confused that is NF3 polar or nonpolar? I will clarify all confusion about it.

I received messages from my students, and they are still confused because they say that the book says NF3 isn’t polar, but the internet says that Nf3 is polar. 

So let’s discuss everything in detail what’s the logic and why somewhere NF3 is polar and sometimes nonpolar.

Nitrogen trifluoride is an inorganic chemical compound which formula is NF3. The nitrogen-fluorine gas is colorless, and sometimes it’s non-flammable, which is difficult to burn.

The nitrogen trifluoride smell has a stale(musty) smell and has a potent greenhouse gas.


The formula of nitrogen trifluoride is NF3.

Molar Mass:

The molar mass of the nitrogen trifluoride is 71 g/mol.

Is NF3 Polar or Nonpolar?

Nf3 polarity explained
NF3 is polar

Reason 1:

The NF3 is polar because NF3 has a lewis structure, and the molecules form in a pyramidal shape. The lewis structure extends the concept of electrons and shows each atom position in molecules’ structure using its chemical bonds. 

Reason 2:

The NF3 is polar because they distribute bonding electrons, and its shape also balances the polarity.

Reason 3:

The NF3 is polar nitrogen in the NF3 and has five valence electrons, representing a lone pair on the structure. The lone pair will reduce the dipole moment on the molecule.

With that, it’s also essential to know about the BrF5 and NO2+ polarity.


Simple is that NF3 is polar, but make sure you know about polar and non-polar, so continue reading to clarify all your confusion.

Difference Between Polar And Nonpolar Molecules With Examples

Polar Molecules:

If two atoms do not share the electrons equally in a covalent bond, the polar molecules occur. 

The dipole interactions occur when the positive end of the molecules interacts with another end of negative molecules.

Dipole usually happens when the electronegativity of the values of each atom is different. It depends if there are more differences, so it forms an ionic bond; otherwise, if the difference is less forms a polar covalent bond.

If you are still confused about how you can recognize the less and more difference, the difference of the electronegativity between two atoms is 0.5 and 2.0, so those atoms will form a polar covalent bond.


If the difference of the electronegativity between two atoms is greater than two, those atoms will form an ionic bond.

Example Of Polar Molecules:

These are the example of polar molecules.

  1. Ammonia, The formula of ammonia is NH3
  2. Ethanol, The formula of ethanol is C2H6O
  3. Water, The formula of water is H2O
  4. Sulfur dioxide, The formula of water is SO2
  5. Hydrogen sulfide, The formula of Hydrogen sulfide is H2S

Nonpolar Molecules:

When the molecules share the electrons equally in a covalent bond or the molecules with zero dipole moment are called non-polar molecules. 

The atoms which are available in the molecules will have equal charge distribution for that no polarity will occur.

If the difference in electronegativity between the two atoms is less than 0.5, the bond is considered non-polar.

Example Of Polar Molecules:

These are the example of non-polar molecules.

  1. Benzene, The formula of Benzene is C6H6
  2. Methane, The formula of Methane is CH4
  3. Carbon dioxide, The formula of Carbon dioxide is CO2
  4. He, Ne, Ar is also an example of non-polar molecules. These are noble gases, which are technically atoms, not molecules.
  5. They are also non-polar molecules(H2, N2, O2, Cl2).


I have discussed everything in detail about polar and nonpolar molecules with examples so read it and try to understand everything. If you didn’t get it try to read again and again to understand everything properly.

Is NF3 Ionic Or Covalent

Reason 1:

The nitrogen trifluoride(NF3) is a polar covalent bond because the electrons are shared between fluorine and nitrogen. Let suppose if the two fluorine atoms come together, they will make a nonpolar covalent bond. Also, if the two nitrogen atoms share the electrons equally, it will make nonpolar covalent bonds.

Reason 2:

The nitrogen and fluorine are non-metals and have an electronegativity difference—the covalent bond forms between two non-metals.

Reason 3:

The NF3 is a covalent bond. It is more electronegative because it has 5 electrons in its 2P shell.


Simple is that NF3 is covalent because of the above three reasons.

Bond Angle Of NF3

The bond angle of NF3 was 107° in ammonia, but it’s reduced, and nowadays the bond angle of NF3 is 101.9°. The main reason why the bond angle of NF3 reduces due to the electronegative fluorines, The electronegative fluorines pull the electrons towards N-F bonds, which reduces the interelectronic repulsions so that umbrella of the NF3 closeup.

bond angle of nf3
NF3 & NH3

Are you wondering why the bond angle of NF3 is less then NH3 because the N is more electronegative rather than H, so that’s why that large number of electrons will go towards to the N, which will keep away the bonds from the central atom. So that the H−N−H angle will decrease.

If I talk about the NF3, so F is more electronegative rather than N, Therefore, the only pair cloud on the N extends across the N-F junction.


Simple is that the bond angle of NF3 is 101.9°.

What Is NF3 Hybridisation

Before proceeding to the hybridization of NF3, I want you to clarify your confusion about hybridization.

The hybridization is the process of mixing two atomic orbitals which form a new atomic orbital. The new orbitals of electrons hold the same number of electrons as the hold ones.

The reason why hybridization concept introduced it’s because of best explanation and C – H bonds in molecules are identical such as methane.

If someone asks you that what is NF3 hybridization then directly answer it that the hybridization of NF3 is sp3. The reason why the hybridization of NF3 is sp3 it’s because of the pyramidal structure of molecules in NF3.


The hybridization of NF3 is sp3 because NF3 has a pyramidal structure that’s why NF3 has sp3 hybridization.

NF3 Lewis Structure

Do you want to know about NF3 lewis structure? Check out the image.

What is the Lewis structure of nf3?
Structure of lewis NF3

The lewis structure of NF3 is mostly similar to the NH3 and NCl3 if I talk about the NF3 lewis structure, so in this structure, all of the hydrogen gas goes outside, The valence structure of NF3 has total eight valence electrons and the hydrogen only needs two valence electrons.

Still, you are confused to draw the lewis structure of NF3? Watch this video.

NF3 Molecular Geometry

Do you want to know what is the molecular geometry of NF3 is? Before proceeding to it, I want you to learn about molecular geometry first. The molecular geometry describes the shape of the molecules, from the location of nuclei and its electrons.

NF3 Molecular Geometry
Tetrahedral molecular geometry shape

The molecular geometry of NF3 is Trigonal Pyramidal. The Trigonal Pyramidal is a molecular shape when there are three bonds, one of the lone pair bonds in the central of the item as given in the picture.

You might be wondering why NF3 is pyramidal? Generally, the nitrogen consists of 3 covalent bonds and five valence electrons. The NF3 have four pairs of electrons which form a regular tetrahedron. Covalent bonds occupy three of the four points of the tetrahedron, providing a triangular pyramidal geometry.

The tetrahedron is also called tetrahedra and a triangular pyramid and has four triangle faces, six straight edges, and four vertex corners.


The molecular geometry of NF3 is Trigonal Pyramidal.

Related Questions

Is nf3 a covalent bond?

Yes, NF3 is covalent bond I have explained the reason above in details why it’s a covalent bond.

What is the name for nf3?

The name of NF3 is Nitrogen trifluoride.

Is nf3 dipole dipole?

Yes, NF3 held together with dipole dipole forces.

Final Thoughts

That was all about is NF3 polar or non-polar, I hope now your all confusion is clear that NF3 is polar because of the molecules in the NF3 form in the pyramidal shape.

I have explained three reasons in details that why NF3 is polar read it carefully to clarify your all confusion.

If I talk about the difference between polar and non-polar molecules so simple is that in polar molecules, two items don’t share electrons equally and in non-polar molecules share electrons equally.

The NF3 is a covalent bond because it has more electronegative.

Do you think I have missed something about NF3 topic? Let us know in the comments section I will add them.

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